Chocolate Orange Cake with Ganache and Grand Marnier

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This Chocolate Orange Cake is made with a whole orange – peel, pith and all – boiled until soft and blended straight into the batter. The result is a fresh, zesty and incredibly moist orange sponge, brushed with Grand Marnier and layered with silky dark chocolate ganache.

A layered chocolate orange cake with frosting, topped with orange zest, with one slice removed.

The idea comes from my Whole Lemon Cake, which uses the same boiled-fruit trick. Using the whole fruit captures all the fragrant oils in the peel, so the cake tastes of real orange rather than a faint hint of zest or the slightly artificial note of orange extract.

Chocolate and orange has been my favorite flavor pairing since childhood (blame the Terry’s Chocolate Oranges that found their way to Athens whenever someone visited England). This is the grown-up version: A tender golden sponge, a hint of orange liqueur and lots of rich chocolate. Perfect for birthdays, Christmas or any excuse really.

This amazing cake stays fresh and moist for days at room temperature so you can sneak a cheeky slice whenever you are in a mood for a treat.

Why You’ll Love It

  • Real orange flavor: The whole boiled orange gives a fresh, zesty sponge – no extract needed.
  • Seriously moist: Blended orange, buttermilk and ground almonds keep the crumb soft for days.
  • Velvety crumb: Rubbing the butter into the dry ingredients first (the reverse-creaming method) gives a fine, even texture.
  • Grown-up and festive: A brush of Grand Marnier and plenty of dark chocolate ganache make it a proper celebration cake.
  • Make-ahead friendly: Boil the orange up to two days ahead and freeze the sponges if you like.
A frosted chocolate orange cake topped with piped frosting swirls and zest, sitting on a white plate with a bowl of oranges in the background.

Here’s What You’ll Need

The sponge follows the same reliable base as my lemon cake. Full quantities are in the recipe card below – and if you need to convert between cups and grams, my baking conversion calculator has you covered.

  • Orange – one medium organic / unwaxed navel orange (Jaffa orange in the UK), scrubbed. Navel oranges are seedless with a thin pith, which keeps the cake sweet rather than bitter.
  • Butter – unsalted and cubed, at cool room temperature so it rubs into the flour without melting.
  • Sugar – regular granulated sugar.
  • All-purpose flour, almond flour and cornstarch – the almonds add moisture and the cornstarch softens the crumb, a little like using cake flour.
  • Baking powder and baking soda – the baking soda balances the acidity of the orange and buttermilk, while the baking powder gives a steady, even rise.
  • Buttermilk and eggs – both at room temperature so the batter stays smooth.
  • Olive oil – just 2 tablespoons keeps the sponge extra moist and tender. Use a mild or light olive oil so it doesn’t overpower the orange.
  • Grand Marnier – the cognac-based orange liqueur. Cointreau or triple sec work too, or see the alcohol-free option in the recipe notes.
  • Chocolate chips, heavy cream (double cream), golden syrup and butter – for a glossy, silky ganache with a pinch of sea salt. For the golden syrup, I use Lyle’s Golden Syrup. Use good quality semi-sweet chocolate chips with around 50–70% cocoa solids.
Baking ingredients for a chocolate orange cake arranged on a grey surface, including bowls of flour, sugar, cubed butter, mashed pumpkin, eggs, and citrus zest.

Is Orange Peel Safe to Eat?

Most supermarket oranges are coated with wax after harvest, and many are also treated with fungicides such as imazalil to stop mold. UK packs list these treatments on the label (here’s a typical example). They are legal and regulated, but the limits assume we peel our oranges rather than eat the skin – which is why some packs say the peel isn’t suitable for eating.

  • Best option: Buy organic or unwaxed oranges, as synthetic post-harvest fungicides are not allowed on organic fruit.
  • Otherwise: Scrub the orange under warm water with a brush, which removes a good share of surface residues, and discard the first boiling water (see Boil the Orange below).

How to Make Chocolate Orange Cake

↓ For the full ingredients and detailed method, jump to the recipe card.

Make the Ganache

  1. Add the cream, golden syrup, chocolate chips and butter to a large mixing bowl. Microwave in short 30–40 second bursts until the cream is warm and the chocolate starts to melt, then leave to rest for a few minutes.
  2. Stir gently from the center outward with a long, narrow spatula, moving in very small circles, until the ganache is glossy and smooth. For an even glossier, thicker ganache, blend it with an immersion blender, keeping the head fully immersed so you don’t whisk in any air bubbles.
  3. Cover the surface of the ganache with plastic wrap and leave to cool at room temperature for 4–5 hours, or evn overnight, until thick and spreadable. Don’t refrigerate it, as this can make the ganache hard and dull its shine.
Two side-by-side overhead views showing a hand using a spatula to stir dark chocolate into a lighter liquid base for a chocolate orange cake in a mixing bowl.

Baker’s tip

Give the ganache time

Ganache needs 4–5 hours at room temperature to thicken enough to spread and pipe, which is why it is made first – or even the day before. Warm ganache slides off the cake and squeezes out between the layers. If it sets too firm, warm it for a few seconds in the microwave and stir until smooth again.


Boil the Orange

  1. Preheat the oven to 320°F (160°C). Mist three 8-inch round cake pans with cake release and line the bottoms with parchment paper.
  2. Place the scrubbed orange in a pot of boiling water and simmer until it is completely soft all the way through, about 20 minutes. If you are using a conventional (waxed) orange, simmer it for 5 minutes first, then drain and start again with fresh water. Let cool.
  3. Cut it open and remove any seeds and the hard stem end.
A hand uses a knife to cut orange segments on a wooden cutting board for a chocolate orange cake.
  1. Blend everything – peel and all – in a food processor until you have a smooth, bright orange paste. You will need scant 1 cup (200g) for the cake, so you may have a little left over.
A food processor container filled with orange slices before and after being blended into a puree for a chocolate orange cake.

Make the Batter

  1. Whisk the buttermilk, eggs, olive oil and blended orange together in a jug.
A glass measuring cup holds raw eggs, milk, and grated cheese for a chocolate orange cake recipe, with a small bowl of white powder nearby.
  1. In the bowl of a stand mixer fitted with the paddle (or a large bowl with a hand mixer), stir together the flour, sugar, ground almonds, cornstarch, baking powder, baking soda and salt.
  2. Add the cubed butter and beat on low speed until the mixture looks like damp sand with no large lumps of butter.
  3. Pour in the wet ingredients and beat on low to medium speed until the batter is smooth, scraping down the bowl once or twice.
Beating cubed butter into the dry ingredients with a hand mixer until sandy, then mixing in the wet orange mixture to a smooth batter.

Bake the Cake Layers

  1. Divide the batter evenly between the three prepared pans and level the tops. Bake for about 20 minutes, until a toothpick inserted in the center comes out clean.
  2. Cool in the pans for 5–10 minutes, then turn out onto a wire rack. Cover with plastic wrap while they cool to lock in the moisture.
Spreading orange cake batter evenly in a round cake pan with an offset spatula.

Assemble the Cake

  1. Warm the Grand Marnier in a small saucepan, then brush it over the cooled cake layers so it soaks in.
  2. Place the bottom layer on a serving plate and pipe or spread with a generous layer of ganache. Top with the second layer, pressing down gently, and repeat with the third.
  3. Cover the whole cake with a layer of ganache, smoothing the sides with a bench scraper or offset spatula.
  4. Swirl or pipe the remaining ganache over the top using a piping bag and large tip, and decorate with the orange strips, if using.
A hand uses a piping bag to add decorative swirls of chocolate frosting to the top of a chocolate orange cake.

Storage and Freezing

  • Make ahead: Boil and blend the orange up to 2 days ahead and keep the paste in the fridge. The ganache can be made up to a day ahead and kept covered at room temperature.
  • Store: Keep covered at cool room temperature for up to 4 days, or in the fridge for up to 6 days. Take it out 30 minutes before serving so the ganache softens.
  • Freeze: Wrap the cooled, unfrosted sponges tightly in plastic wrap and foil and freeze for up to 3 months. Thaw overnight in the fridge, still wrapped, before assembling.
Chocolate orange layer cake with a slice cut away, showing three golden orange sponge layers filled with chocolate ganache.

You’ll Also Love…

A slice of three-layer chocolate orange cake on a yellow plate with a fork.

Frequently Asked Questions

Is orange peel safe to eat?

Yes, but most supermarket oranges are waxed and many are treated with post-harvest fungicides, with residue limits set on the basis that the peel is not eaten. For any recipe using the whole fruit, choose organic or unwaxed oranges, or scrub conventional oranges well and discard the first boiling water.

Do I need to peel the orange?

No. The whole orange goes into the cake – peel, pith and flesh. Just remove the seeds and the hard stem end after boiling.

Will the cake taste bitter?

Not if you use a thin-skinned navel orange and boil it until completely soft, which mellows the pith. Avoid Seville oranges, which are far too bitter for this cake.

Can I make this cake without alcohol?

Yes. Brush the sponges with a simple orange syrup made by simmering fresh orange juice with a little sugar.

Can I use Cointreau instead of Grand Marnier?

Yes. Cointreau or triple sec work well. They are a little sharper and less rich than Grand Marnier, which is made with cognac.

Can I use a different citrus fruit?

Yes. Try two or three clementines or a blood orange instead. For the lemon version, see my Whole Lemon Cake.

Can I make the cake ahead?

Yes. Boil and blend the orange up to 2 days ahead and bake the sponges the day before. The assembled cake keeps for up to 5 days in the fridge.

Can I freeze chocolate orange cake?

Yes. Freeze the unfrosted sponges, well wrapped, for up to 3 months and thaw overnight in the fridge before filling and frosting.

Does the cake need to be refrigerated?

It is fine at cool room temperature for up to 2 days. After that, or in a warm kitchen, keep it in the fridge and bring it back to room temperature before serving.


Please leave a comment and rating if you try this Chocolate Orange Cake, follow me on Pinterest for more easy recipes and don’t forget to tag me on @Instagram or TikTok so I can see your creations!

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Chocolate Orange Cake with Grand Marnier

A fresh, zesty and ultra-moist orange sponge made with a whole boiled orange, brushed with Grand Marnier and layered with silky dark chocolate ganache.
Prep Time: 30 minutes
Cook Time: 40 minutes
Ganache cooling: 4 hours
Total Time: 5 hours 10 minutes
Servings: 16 slices
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Ingredients

For the Cake

  • 1 medium orange , ideally seedless
  • ¼ cup (60ml) buttermilk
  • 2 tbsp olive oil
  • 3 large eggs room temperature
  • 1 ¾ cups (330g) sugar
  • 2 cups (260g) all-purpose flour (= plain flour)
  • ½ cup (60g) ground almonds or almond flour
  • 1 tbsp cornstarch (= cornflour)
  • 1 tsp baking powder
  • 1 tsp baking soda (= bicarbonate of soda)
  • ⅓ tsp salt
  • ⅞ cup (200g) unsalted butter cold, cubed

For the Ganache

Assembly and Decoration

  • ⅓ cup (80ml) Grand Marnier or other orange liqueur
  • 2 tbsp orange strips optional

Instructions 

Make the Ganache

  • Add the cream, golden syrup, chocolate chips and butter to a large mixing bowl. Microwave in short 30–40 second bursts until the cream is warm and the chocolate starts to melt. Rest for a few minutes.
    1 ½ cups (375ml) heavy cream, ⅓ cup (100g) golden syrup, 2 cups (370g) semi-sweet chocolate chips, ¼ cup (65g) unsalted butter, 1 pinch sea salt
  • Use a long, narrow spatula to stir gently from the center outward, moving in very small circles, until the chocolate has melted and the ganache is glossy and smooth.
  • For an even glossier, thicker ganache, blend it with an immersion blender, keeping the head fully immersed. Cover the surface with plastic wrap and leave to cool at room temperature for 4–5 hours or overnight. Do not refrigerate – this can make the ganache hard and dull its shine.

Boil the Orange

  • Preheat your oven to 320°F (160°C). Mist three 8-inch round cake pans with cake release and line the bottoms with parchment paper.
  • Place the orange in a pot of boiling water and simmer until it is completely soft all the way through, about 20 minutes. Let cool.
    1 medium orange
  • Slice it open and remove any seeds. Transfer the pieces to a food processor and blend until you have a smooth paste. You will need scant 1 cup (200g) of the blended orange for the cake, so you may have some left over.

Prepare the Wet and Dry Ingredients

  • In a small bowl, whisk together the buttermilk, oil, eggs and blended orange paste. Set aside.
    ¼ cup (60ml) buttermilk, 2 tbsp olive oil, 3 large eggs
  • In the bowl of a stand mixer fitted with the paddle attachment (or a large mixing bowl), combine the flour, sugar, ground almonds, cornstarch, baking powder, baking soda and salt. Stir briefly on low speed to combine.
    2 cups (260g) all-purpose flour, 1 ¾ cups (330g) sugar, ½ cup (60g) ground almonds, 1 tbsp cornstarch, 1 tsp baking powder, 1 tsp baking soda, ⅓ tsp salt

Mix and Bake

  • Add the cubed butter to the dry ingredients. Beat on low speed until the mixture looks sandy and uniform, with no large chunks of butter remaining.
    ⅞ cup (200g) unsalted butter
  • Pour in the wet buttermilk mixture. Beat on low to medium speed until the batter is completely smooth, scraping the bottom and sides of the bowl with a spatula so everything is evenly mixed.
  • Divide the batter evenly between the prepared pans and level the tops. Bake for about 20 minutes, or until a toothpick inserted into the center comes out clean.
  • Cool the cakes in their pans for 5–10 minutes, then carefully turn them out onto a wire rack. Cover with plastic wrap while they cool to lock in the moisture.

Assemble and Decorate

  • Warm the Grand Marnier in a small saucepan, then brush it over the cake layers so it soaks in.
    ⅓ cup (80ml) Grand Marnier
  • Place the bottom cake layer on a serving plate. Pipe or spread a generous layer of ganache over it.
  • Top with the second cake layer, pressing down gently to secure, and repeat with the third. Cover the entire cake with a layer of ganache, smoothing the sides with a bench scraper.
  • Swirl or pipe the remaining ganache over the top of the cake and decorate with the orange strips, if using. Keep the cake covered and store at room temperature for up to 4 days.
    2 tbsp orange strips

Notes

  • Make ahead: The orange can be boiled and blended up to two days ahead. The ganache can be made up to a day ahead to allow plenty of time for it to cool and thicken.
  • Alcohol-free: Swap the Grand Marnier for a quick orange syrup – simmer fresh orange juice with a spoonful of sugar for a few minutes and brush it over the sponges.
  • Other liqueurs: Cointreau, triple sec or a splash of dark rum all work well.
  • Milk chocolate ganache: For a sweeter, more kid-friendly cake, use milk chocolate and slightly less cream, as milk chocolate sets softer.
  • Chocolate sponge: Prefer chocolate all the way through? Try my Terry’s Chocolate Orange Cake with a glossy chocolate orange glaze.
  • No food processor: A stick blender does the job, or push the soft orange through a sieve.

Nutrition

Calories: 556kcal | Carbohydrates: 56g | Protein: 6g | Fat: 34g | Saturated Fat: 19g | Polyunsaturated Fat: 2g | Monounsaturated Fat: 9g | Trans Fat: 1g | Cholesterol: 96mg | Sodium: 250mg | Potassium: 229mg | Fiber: 3g | Sugar: 39g | Vitamin A: 813IU | Vitamin C: 4mg | Calcium: 66mg | Iron: 3mg

Nutritional information is always approximate, and will depend on quality of ingredients and serving sizes.

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Troubleshooting

ProblemCauseFix
Cake tastes bitterThick pith, seeds left in, or the orange was not boiled long enoughUse a thin-skinned navel orange, remove every seed and boil until completely soft. Discarding the first batch of water helps too
Orange paste is lumpyOrange not quite soft, or too little liquid to blendSimmer a little longer, then blend with a spoonful of the cooking water
Cake is dense or heavyCold eggs or buttermilk, or the batter was overmixedBring everything to room temperature and mix only until smooth
Cake sank in the middleUnderbaked or the oven door was opened too earlyBake until a toothpick comes out clean and avoid opening the oven in the first 20 minutes
Sponge is soggyToo much liqueur, or brushed onto a hot cakeBrush lightly onto slightly warm (not hot) sponges
Ganache is too runnyNot cooled long enoughLeave at room temperature to thicken, or chill for 10 minutes at a time, stirring in between
Ganache is grainy or oilyCream too hot or the ganache was overworkedWhisk in a tablespoon of warm milk or cream to bring it back together

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